Phys. Rev. B 56, 1928 (1997).

Calculation of atomic geometry, electronic states and bonding for the S-deposited InP(110) surface


M. Çakmak and G.P. Srivastava

Department of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL, UK


Abstract

Ab initio calculations, based on pseudopotentials and the density functional theory, have been made to investigate the equilibrium atomic geometry, electronic states and bonding of S adsorbates on the InP(110) surface with (1x1) periodicity. For non-reacted half-monolayer coverage of S, we find that the interchain bridging geometry has the lowest total energy. For non-reacted full monolayer coverage the epitaxially continued layer structure is found to be the most energetically favourable, and exhibits a good semiconducting nature. We have also studied four geometrical models which involve reaction of S atoms with the substrate. For an ordered reacted model with the adsorbate S atoms exchanged with their neighbouring P atoms, the average vertical distance between the top two layers is 1.98 A, which is in agreement with a recent result obtained from x-ray standing wave analysis, but is characterized by a small band gap.